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Abstract
Soluble-protein-free Radiation-vulcanised Natural Rubber
Latex
The effect of water-soluble polymers (WSPs), such
as polyvinyl alcohol (PVA) and polyvinyl pyrolidone (PVP), on radiation-vulcanised
natural rubber latex (RVNRL) was investigated. Extractable protein measurements
showed that mixing of WSP into RVNRL, followed by centrifugation, effectively
reduced the extractable protein from RVNRL. However, extractable protein
could be further effectively removed from RVNRL by adding low-molecular-weight
PVA (LMW-PVA) and PVP (LMW-PVP). It was further observed that, using 3 p.h.r
of either LMW-PVA or LMW-PVP followed by 20 min leaching in 1% ammonia solution,
was sufficient to produce RVNRL free of soluble proteins. Based on these
results a new process has been developed by the incorporation of LMW-WSP
into RVNRL and centrifugation, followed by leaching. Tensile properties
such as tensile and tear strength, were comparable to those of conventional
RVNL. Fourier Transform Infrared measurements showed that most of the WSP
was removed from RVNRL during the centrifugation process. The viscosity
of the RVNRL was not much affected by the addition of LMR-WSP.

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