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Abstract
Cure Characteristics and Mechanical Properties of Vulcanised Natural Rubber by Using a New Binary Accelerator System
Natural Rubber was vulcanised with a new binary accelerator
system: 1-phenyl-2, 4-dithiobiuret (DTB)/2, 4-morpholinothio benzothiazole
sulphenamide. The processing characteristics of the mix showed a significant
reduction in cure time with the addition of DTB. Mechanical properties of
the vulcanisates showed a better performance. DTB does not change the stress-strain
nature of natural rubber. The observed mechanical properties could be correlated
with network characteristics of the vulcanisates. The chemical characterisation
of the vulcanisates was done by swelling measurements. The crosslink density
obtained by swelling measurements was compared to that obtained by stress-strain
measurements. Based on the processing, mechanical and chemical characterisation
of the vulcanisates an optimum concentration of DTB was found.

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