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Abstract
NR Latex Vulcanisation - Prevulcanisation and Post-vulcanisation
of Dipped NR Latex Films
The tensile properties results of NR dipped
latex films prepared by prevulcanisation process and post-vulcanisation
imply that the standing period during the latex stage dominates the extent
of crosslinking in the latex films. Further crosslinking does not seem to
occur in dry latex films as reflected by its modulus values. The results
support the idea that most crosslinking in NR latex occurs during the latex
stage. Leaching improves the tensile strength and modulus when the latex
films were conditioned under low humidity. The presence of water in the
dry latex films during leaching may indicate water as a medium for further
crosslinking to occur, but the reduction of modulus of the films when conditioned
under wet humidity contradicts this idea. Mooney-Rivilin plots of prevulcanised
and post-vulcanised latex films prepared from a similar latex mix further
confirm that most of the crosslinking occurs during the latex stage. It
is concluded from the chemical probe study that the crosslinks in sulphur-vulcanised
dipped NR latex films are predominantly polysulphidics.

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